Acid Blue 80 CAS #4474-24-2

Acid Blue 80, CAS No. 4474-24-2, its chemical name is Acid Blue 80, C.I. Acid Blue 80, Acid Brilliant Blue P-3R, etc.
It is a dark blue crystalline powder, easily soluble in water, the aqueous solution is dark blue, and it is magenta when hydrochloric acid or sodium hydroxide is added. Its molecular formula is C_{32} H_{28} N_{2} Na_{2} O_{8} S_{2}, the molecular weight is 678.683, the melting point is about 300 ºC, the flash point is greater than 300 ºC, and the refractive index is 1.679.
Acid Blue 80 is mainly used for dyeing wool, silk, nylon and their blended fabrics, and can also be directly printed on wool and silk fabrics.
In terms of production, it is usually prepared by condensing 1,4-dihydroxyanthraquinone with mesitylidine (2,4,6-trimethylaniline), then sulfonating with oleum, and salting out. Specifically, a certain amount of mesitylidine, hydrochloric acid, 1,4-dihydroxyanthraquinone, boric acid, and glacial acetic acid are added to a reactor, carbon dioxide is introduced, heated, and zinc powder is added for reaction, and then the reaction liquid is poured into preheated sulfuric acid, refluxed, filtered, and washed with water until neutral, and then refined with sodium carbonate solution to obtain a filter cake, and finally the filter cake is reacted with oleum, and the finished dye is obtained after treatment.

Acid Blue 80 CAS #4474-24-2

Product Name: ACID BLUE 80
Synonyms: 4,4’-(1,4-anthraquinonylenediimino)di-2-mesitylenesulfonicacidisodiums;4,6-trimethyl-)bis(disodiumsalt;CI 61585;ACID BLUE 80;acid blue 80 (C.I. 61585);Acid Blue 80 (C.I.);sodium 3,3-(9,10-dioxoanthracene-1,4-diyldiimino)bis(2,4,6-trimethylbenzenesulphonate);Weakl Acid Brilliant Blue RAW
CAS: 4474-24-2
MF: C32H31N2NaO8S2
MW: 658.72
EINECS: 224-748-4
Product Categories: pigment;Stains&Dyes, A to;A;Stains and Dyes;Organics
Mol File: 4474-24-2.mol
ACID BLUE 80 Structure
ACID BLUE 80 Chemical Properties
Melting point >300 °C(lit.)
density 1.537[at 20℃]
Colour Index 61585
Water Solubility 10.95g/L at 20℃
InChIKey UHXQPQCJDDSMCB-UHFFFAOYSA-L
LogP -1.304 at 20℃
EPA Substance Registry System C.I. Acid Blue 80 (4474-24-2)
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 26-37/39
WGK Germany 2
RTECS DB6083000
MSDS Information
Provider Language
ACROS English
SigmaAldrich English
ACID BLUE 80 Usage And Synthesis
Chemical Properties dark blue crystalline powder
Uses Acid Blue 80 is a dye/stain. Dyes and metabolites.
Preparation 1,4-Dichloroanthracene-9,10-dione?(1 Moore) or 1,4-Dihydroxyanthracene-9,10-dione (1 Moore) and 2,4,6-Trimethylbenzenamine(2 Moore) condensation, stlfonation, and translated into sodium salt.
Hazard Moderately toxic by ingestion.
Flammability and Explosibility Non flammable
Properties and Applications blue. Red light blue powder, soluble in water, but the solution for a long time have placed precipitation phenomenon. The strong sulfuric acid dyes is red light blue, green light blue to dilute; In nitric acid are brown. Water solution is deep blue, add hydrochloric acid or sodium hydroxide are in product blue. Used for wool, silk, polyamide fiber and its blended fabric dyeing, dyeing scattered hair, tops, yarn packages, socks and knitting yarn and so on, also can be in wool and silk fabric printing directly, it can also be used in leather dyeing.

Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO 6 3 4 4 3-4 4 2
AATCC 4-5 4-5 4-5 4-5 4-5 4-5
ACID BLUE 80 Preparation Products And Raw materials
Raw materials Ethanol–>Sodium hydroxide–>Sulfuric acid–>Acetic acid–>FUMING SULFURIC ACID–>Orthoboric acid–>1,4-Dihydroxyanthraquinone–>Crystal Violet–>2,4,6-Trimethylaniline–>1,4-DICHLOROANTHRAQUINONE–>1,4-DICHLOROANTHRAQUINONE–>2,4,6-Trimethylaniline–>1,4-Dihydroxyanthraquinone

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